We investigated the effectiveness of plant-based bio-additives – rhubarb, lingonberry, and blueberry (0.1–1%) – as natural UV absorbers in biodegradable polymers polylactide (PLA) and polycaprolactone (PCL). A novelty of this work is the direct use of plant-based raw materials as UV absorbers in polymers. We performed Fourier transformed infrared spectroscopy (FT-IR) and UV-Vis analysis of the bio-additives, determined the ultraviolet protection factor (UPF) for the polymer samples, and evaluated their physicochemical properties (structural changes, colour, hardness, surface energy) after weathering (PLA) and thermo-oxidative (PCL) aging. Spectroscopic tests confirmed the presence of UV-A/UV-B-absorbing chromophores in the additives. Samples with 1% berries had excellent UV protection (UPF 40–50+), while PLA and PCL containing 1% rhubarb had lower UPF values (around 22), indicating good UV blocking properties. After aging, PLA-containing berries showed a significantly lower carbonyl index (CI), indicating reduced photodegradation. For PCL with lingonberry, this additive gave the greatest reduction in thermo-oxidative degradation (lowest CI). All plant additives increased material hardness by acting as nucleating agents; they increased the crystallinity of polyester, and aging further strengthened this effect. Bio-additives, especially berries, can increase the hardness and UV resistance of polymers and limit material aging. These polymer compositions are suitable for packaging materials.

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This study investigates the structure–property relationships of multi-functional urethane acrylate resins designed as photoreactive binders for UV-curable nail coatings. Four systems were examined: a commercial resin urethane dimethacrylate (UDMA), a bio-based acrylated epoxidized soybean oil (AESO), and two newly synthesized bio-based urethane acrylates derived from 1,3-propanediol (PDO–UA) and eugenol (EUG–UA). Photopolymerization kinetics were analyzed by realtime FTIR, while the properties of the cured coatings were also determined. The mechanical and thermal behavior of selfsupporting polymer films was evaluated by tensile testing and DSC analysis. The UDMA network exhibited the highest crosslink density, reflected in its high modulus (≈0.5 GPa), tensile strength (≈15 MPa), and Tg (≈60°C), making it suitable for use as a top coat. AESO showed moderate stiffness and flexibility, whereas PDO–UA and EUG–UA formed soft, low-Tg (–12 and –17°C) and highly deformable networks typical of elastomeric materials. The combined mechanical and thermal results confirmed that crosslink density strongly governs coating performance and applicability. This study demonstrates that blending UDMA with bio-based oligomers enables the design of sustainable, UV-curable nail lacquers with an optimal balance of hardness, flexibility, and adhesion to the natural nail plate.

We report a green route to Ag–TiO₂ nanocomposites using an Allium tuberosum extract, rich in organosulfur and polyphenolic constituents, as a dual-function biogenic reducer and stabilizer, enabling efficient Ag⁺→Ag⁰ conversion and capping of Ag–TiO₂ without the use of harsh reagents. The nanocomposites are formulated into chitosan-based inks for direct ink writing (DIW) of porous, mechanically robust, reusable membranes (optimal formulation T@5Ag–5ATE–CS) with a homogeneous Ag dispersion. Multiscale characterization (SEM/TEM, XRD, FTIR, UV–vis DRS, EDS mapping) confirms metallic Ag⁰ uniformly decorating TiO₂ and an extended visible-light response attributable to strong localized surface plasmon resonance. Under near-UV/visible irradiation, the membranes decolorize Remazol Midnight Black RGB dye with pseudo-first-order kinetics, yielding k_app up to 5.99·10^–3 min^–1 with R² ≈ 0.99 and outperforming pristine TiO₂. Response surface methodology identifies an optimum at pH 5.67, 28.87 mg·L^–1 dye, and 0.0257 g catalyst, delivering a predicted 96.41% versus experimental 95.07% removal (validation error 1.39%) with excellent model statistics (R² ≈ 0.995). The combined effects of Allium-tuberosum-assisted Ag plasmonics, TiO₂ photocatalysis, and chitosan-enhanced adsorption underpin the high photocatalytic activity and reusability, highlighting a scalable, eco-friendly pathway to printable photocatalytic/antimicrobial membranes for wastewater treatment.

This study investigates the interaction between poly(butylene adipate-co-terephthalate) (PBAT) and amber powdered waste (AbW) from jewelry at different filler concentrations (0, 1, 2.5, and 5 wt%) obtained via melt mixing in a corotating twin screw extruder. The resulting materials were pelletized and processed using two techniques: 1) cast film extrusion and 2) injection molding. The shaped specimens exhibited excellent interfacial adhesion. Thermal behavior, as assessed by Vicat softening temperature (VST), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA), showed minimal variation among the composites. Despite similar melt flow rate (MFR) values among the samples, the incorporation of AbW affected the behavior of the polymer during cast film extrusion. Consequently, the composite films exhibited lower tensile mechanical parameters (tensile strength, Young’s modulus, stress and strain at break) compared to the neat PBAT film. In turn, the injection molded composites showed improved tensile, flexural, and impact parameters compared to their neat counterpart. Additionally, a slight decrease in water contact angle (WCA) suggested increased surface hydrophilicity of the extruded films. These findings demonstrate the potential of AbW as an additive for biopolymer composites with enhanced mechanical performance. The increased surface hydrophilicity is particularly relevant for applications targeting biocompatibility and biodegradability.