Let's talk about the definitions: Bioplastics, biopolymers, biodegradable polymers and others
Vol. 19., No.5., Pages 455-456, 2025
DOI: 10.3144/expresspolymlett.2025.33
DOI: 10.3144/expresspolymlett.2025.33
GRAPHICAL ABSTRACT

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Elumalai Vengadesan, Swaminathan Muralidharan, Dhanjit Das, Thirugnanasambandam Arunkumar
Vol. 19., No.8., Pages 822-842, 2025
DOI: 10.3144/expresspolymlett.2025.63
Vol. 19., No.8., Pages 822-842, 2025
DOI: 10.3144/expresspolymlett.2025.63

The growing need for sustainable materials has stimulated research into eco-friendly composites, with biochar emerging as an important reinforcement in polymer matrices. Biochar is a carbon-rich material produced by pyrolyzing organic biomass, offering various benefits over traditional fillers, including sustainability, waste reduction, and carbon sequestration. This study explores the effects of bamboo biochar as a hybrid reinforcement on the properties of polylactic acid (PLA)-rice husk composites. The present hybrid composites are prepared by varying the bamboo biochar from 5–25% and have better mechanical properties than PLA and its composite reinforced with a rice husk filler. The tensile, flexural, and compressive strengths of 51.5, 166.0, and 77.5 MPa are measured for the biochar percentage of 10%, representing increases of 73.1, 150.0, and 58.2% compared to PLA, and 158.2, 98.6, and 31% compared to the PLA composite with rice husk. Higher tensile and flexural moduli of 1.46 and 7.34 GPa are observed for 10 and 15%, respectively. However, the impact strength decreases with higher biochar content due to increased rigidity. The material’s hardness increases at higher biochar content due to enhanced stiffness. Thermal transition and degradation points rise due to increased crystallinity from the biochar reinforcement’s nucleation effect. Additionally, the hydrophobic biochar reinforcement reduces water absorption of PLA composite from 3.2 to 1.6%.
Guilherme Ribeiro de Carvalho, Rafael Affonso Netto, Camila Delarmelina, Marta Cristina Teixeira Duarte, Liliane Maria Ferrareso Lona
Vol. 19., No.7., Pages 686-696, 2025
DOI: 10.3144/expresspolymlett.2025.52
Vol. 19., No.7., Pages 686-696, 2025
DOI: 10.3144/expresspolymlett.2025.52

In this study, a new plastic film with antiviral and antibacterial properties was developed using modified cassava starch with glycidyltrimethylammonium chloride (GTMAC) and reinforced by crystalline nanocellulose (CNC), called Q-CS/CNC. For comparison, a control film (Q-CS) was produced without the addition of CNC. Elemental analysis revealed a degree of substitution (DS) of 0.552, indicating the replacement of the OH groups of starch by the NR4+ groups of GTMAC during the quaternization reaction. The addition of CNC resulted in significant increases (p < 0.05) of 38.9, 38.2, and 43.1% in thickness, opacity, and water vapor permeability measurements, respectively, compared to Q-CS. Incorporating CNC also contributed to an increase of 43.6% in tensile strength and 109% in stiffness but slightly decreased thermal stability. The Q-CS/CNC film demonstrated efficacy by inactivating 99% of the coronavirus in 1 min and inhibiting the growth of Staphylococcus aureus and Escherichia coli. This action is attributed to the electrostatic interaction of quaternary amino groups, grafted onto starch, with the phospholipid membrane of microorganisms, resulting in the inactivation of these microorganisms. Therefore, these results highlight the potential use of Q-CS/CNC film as antimicrobial packaging, especially against coronavirus.
Seisuke Ata, Takumi Ono, Motonari Shibakami
Vol. 19., No.6., Pages 628-635, 2025
DOI: 10.3144/expresspolymlett.2025.47
Vol. 19., No.6., Pages 628-635, 2025
DOI: 10.3144/expresspolymlett.2025.47

This study demonstrated, for the first time, the successful formation of porous paramylon esters, which were made from euglenoid polysaccharide known as paramylon and short-chain fatty acids, through supercritical CO2 processing. By maintaining a constant ester functional group attached to the paramylon and varying its proportion, distinct porous structures were selectively produced. Solubility parameter estimations indicated that changes in esterification had no significant effect on the solubility of the paramylon esters used in the experiment. Thus, these structural differences are likely attributed to variations in the viscoelastic properties of paramylon esters under supercritical CO2 conditions. Furthermore, thermal conductivity measurements revealed reductions of up to 20%. Intriguingly, substantial decreases in thermal conductivity were observed even at low foaming ratios, achieved through precise control of the porous structure.
Mohammad Mehdi Alighanbari, Firoozeh Danafar, Araam Namjoo, Asma Saeed
Vol. 19., No.1., Pages 15-46, 2025
DOI: 10.3144/expresspolymlett.2025.3
Vol. 19., No.1., Pages 15-46, 2025
DOI: 10.3144/expresspolymlett.2025.3

The environmental and ecological concerns drive researchers to synthesize functional materials using components from natural resources. Nanocellulose (NC), derived from plants, marine animals, or microorganisms, is a green material attracting attention due to its abundance, biocompatibility, and biodegradability. NC’s interstice properties enable the synthesis of functional nanocomposites in forms like aerogels, foams, paper, sheets, or hollow filaments. This review briefly describes NC classification and production while comprehensively presenting its mechanical, rheological, optical, and electrical properties, offering foundational knowledge for future research. Additionally, it highlights recent developments in NC-based products across fields such as papermaking, water treatment, civil engineering, electronics, cosmetics, food, and medicine. For the first time, this paper explores recent advances in NC molecular simulation, providing insights into structure, arrangement, and interactions through molecular dynamic simulation. Finally, future prospects for NC-based applications are discussed to encourage studies addressing current challenges.
Ju Li, Lize Yang, Shuo Chen, Guotao Sun
Vol. 19., No.1., Pages 47-59, 2025
DOI: 10.3144/expresspolymlett.2025.4
Vol. 19., No.1., Pages 47-59, 2025
DOI: 10.3144/expresspolymlett.2025.4

The widespread use of cellulose nanofiber (CNF)-based aerogels is hindered by their limited flame retardancy and mechanical properties. This study addresses these challenges by developing cellulose nanofiber/sodium alginate/fly ash (CNF/SA/FA) aerogel through a one-pot method, utilizing industrial waste fly ash (FA) as a reinforcing material. Various characterization and analytical techniques were employed to evaluate the properties of the CNF/SA/FA aerogel. The findings have revealed that resulting aerogel exhibited excellent thermal insulation performance, with a thermal conductivity of 0.485 W/(m·K), along with an impressive compressive strength of 88.4 kPa and favorable shape processability. Vertical combustion tests demonstrated a V-0 rating, indicating superior flame retardancy, and the aerogel achieved a remarkable 79.16% residual carbon, confirming their effective heat shielding capabilities. Notably, the incorporation of FA significantly enhanced both the thermal and mechanical properties of the composite aerogel, presenting a sustainable and effective solution to optimizing the properties of aerogel for thermal insulation.